"It's
POLLUTION , Stupid! "
by George
Glasser
Scientists
can argue and bicker about the fluoride ion
for eternity and beyond, but the one
indisputable fact that no one can rebut is
the origin of the product most used to
fluoridate drinking water. The pro-fluoridationists
are using captured pollution from phosphate
fertilizer production: Commercial Grade
Fluorosilicic Acid and Sodium
Fluorosilicate. It is not, "simply the
fluoride ion in water," it is a complex
recipe of toxic substances that most
countries have labeled:
Hazardous Air
Pollutants (HAP).
United States
Environmental Protection Agency
Rebecca
Hanmer, Deputy Administrator for Water,
USEPA, 1983, wrote:
" in regard
to the use of fluosilicic acid as a source
of fluoride for fluoridation, this agency
regards such use as an ideal solution to a
LONG-STANDING problem. By recovering
byproduct fluosilicic acid from fertilizer
manufacturing, water and air pollution are
minimized, and water utilities have a
low-cost source of fluoride available to
them."
The Geology
of Florida, 1997, University Press of
Florida, Pg. 143 The Economic and Industrial
Minerals of Florida.
In addition
to uranium, fluorine is an economic
byproduct of phosphoric-acid production. The
fluorine from the rocks reacts with silica
to form SiF 4 gas. During acid production,
this gas is recovered as fluorosilicic acid
(H 2 SiF 6 ) in wet scrubbers that are part
of the environmental-protection equipment. Fluorosilicic acid is widely used in the
preparation of chemical compounds and in the
treatment of public drinking water… Radon,
a daughter product of the uranium-series
decay, remains a major environmental
problem… Gases such as ammonia sulfur oxides,
and fluorine species have caused problems in
the past.
Fluorine
Recovery in the Phosphate Industry:
By H. F. J.
Denzinger, H. J. König and G. E. W. Krüger
ABSTRACT -
Phosphorous & Potassium #103 SEPT/OCT 1979,
pages 33-39
The fluorine
compounds liberated during the acidulation
of phosphate rock are now rightly regarded
as a menace and the industry is now obliged
to suppress emissions-containing vapors to
within very low limits in most parts of the
world. As with any pollution control
operation, it is highly desirable for the
operator of the fluorine scrubber to help
defray at least partially the cost of the
operation.
This article
reviews the chemical and technical
principles of gaseous fluorine compound
removal, the principal types of practical
fluorine recovery processes that have been
developed and their limitations, and
possible methods of utilizing the
fluosilicic acid solutions which these
processes generate.
USEPA OFFICE
OF AIR AND RADIATION
1996, USEPA
Office of Air and Radiation, 40 CFR Part 63
[IL-64-2-5807; FRL-5656-4] RIN 2060-AE40 and
2060-AE44: SUMMARY: Hazardous air pollutants
(HAPs) emitted by the facilities covered by
this proposed rule include hydrogen fluoride
(HF ) ; arsenic, beryllium, cadmium,
chromium, manganese, mercury, and nickel
(HAP metals); and methyl isobutyl ketone (MIBK)
emissions. Human exposure to the HAP
constituents in these emissions may be
associated with adverse carcinogenic,
respiratory, nervous system, dermal,
developmental, and/or reproductive health
effects. "
Patty's
Industrial Hygiene and Toxicology, Vol. 2,
Part A: 4th Edition, 1993.
Chapter 15,
pg. 831-884: Silicon and Silicates,
Including Asbestos, Carl O. Schulz, Ph.D.,
D.A.B.T. Pg. 832
The fourth
revision of this book marks the first time
that the toxicologic aspects of silicon and
its compounds have been discussed in a
separate chapter. Pg. 882-883: 10 Other
Silicon Compounds, 10.1 Silicon Halides
Of the four
silicon tetrahalides (also know as
tetrahalosilanes), only three, the fluoride,
chloride and bromide, are of commercial
significance, with silicon tetrachloride
being of greatest importance. The
tetrafluoride is a gas at room temperature
whereas the tetrachloride and tertrabromide
are fuming liquids. They are prepared by the
direct halogenation of pure quartz or
silicon carbide at elevated temperature and
pressure. The primary u se of silicon
tetrachloride is as the starting material
for the manufacture of high-purity silicon,
amorphous fumed silica and ethyl silicate.
Silicon tetrafluoride is used as a starting
material for fluosilic acid (H2SiF6) for
water fluoridation. The silicon tetrahalides
are readily hydrolyzed to their
corresponding hydrogen halides and silica
upon contact with moisture. For this reason
all three silicon tetrahalides are highly
toxic by either inhalation or ingestion and
can cause severe irritation of the skin and
mucous membranes. In this respect their
occupational hazards are qualitatively
similar to those associated with the
hydrogen halides. No TLVs or OSHA standards
have been developed for these compounds.
Researchers
use molecular silica dioxide precipitated
from a better grade of Fluorosilicic Acid (H
2 SiF 6 ) for cancer research!
R. Eastman,
General Chemistry: Experiment and Theory,
1969; Holt,
Rinehart and Winston, Inc.
"Hydrofluoric
acid has the distinctive property of
attacking glass/sand (silicon dioxide). The
reaction is the attack of a strong Lewis
Base F- (the fluoride ion) on the Si
(silica) atoms, thereby replacing the O
(oxygen) atoms."
AUTHOR:
Saffiotti U, Ahmed N TITLE: Neoplastic
transformation by quartz in the BALB/3T3/A31-1-1
cell line and the effects of associated
minerals . SOURCE: Teratog Carcinog Mutagen;
15(6):339-56 1995 UI: 96310605 ABSTRACT:
Quartz, the most common form of crystalline
silica, was tested quantitatively for
neoplastic transformation in the mouse
embryo cell line, BALB/3T3/A31-1-1. Five
quartz dust samples of respirable size
[Min-U-Sil 5 (MQZ); hydrofluoric-acid-etched
MQZ (HFMQZ); Chinese standard quartz (CSQZ);
DQ12; and F600] all induced significant
levels of neoplastic transformation, showing
dose-dependent increases in the frequency of
morphologically transformed foci at lower
tested doses and a plateau level of response
at higher doses. The plateau levels reached
by the five tested samples did not differ
substantially (maximum transformation
frequencies per 10(5) cells ranging from
53.2 for MQZ to 28.3 for HFMQZ). F600 had
minimal cytotoxicity but transforming
activity comparable to the other samples.
Cells from all tested transformed foci, when
injected s.c. in nude mice, grew as
sarcomas. Cytogenetic analysis showed that
all tested silica-transformed cell lines had
acquired one to five additional marker
chromosomes, of types not seen in untreated
control lines, indicative of induced
chromosomal translocations and
amplification. Increased expression of one
or more of five genes (p53, myc, H-ras, K-ras,
and abl) was observed in several
quartz-transformed cell lines. No
transforming activity was found for hematite
and anatase (both nontoxic), and for rutile
(more toxic than MQZ). Combined exposure
(1:1 w/w per unit culture area) of each of
these dusts with MQZ showed that hematite
and anatase inhibited MQZ toxicity as well
as transformation, whereas rutile markedly
enhanced MQZ toxicity but not MQZ-induced
transformation.
AUTHORS:
Rumiantsev GI; Novikov SM; Mel'nikova NN;
Levchenko NI; Kozeeva EE; TITLE:
Experimental study of the biological effect
of salts of hydrofluosilicic acid SOURCE:
Gig Sanit, ISS 11, 1988, P80-2 SECONDARY
SOURCE ID: TOXBIB/89/212028 MAIN MESH
HEADINGS : Fluorides/*TOXICITY; Liver/*DRUG
EFFECTS, Nervous System/*DRUG EFFECTS,
Silicon/*TOXICITY
Brief History
of flouride in our water.
What does
a company do with the essence of pollution?
In the late
1960's, Ervin Bellack, USEPA chemist and a
manufacturing representative put their heads
together and worked out the ideal solution
to a monumental pollution problem.
The recovered
phosphate fertilizer manufacturing pollution
contained about 19% fluorine. The
concentrated pollution scrubber liquor was
perfect to use as a water fluoridation
agent. It was a liquid and easily soluble in
water unlike sodium fluoride (the waste
product from aluminum manufacturers). It was
also inexpensive, and there was a glut of
the concentrated toxic waste.
Fate also
intervened. The aluminum industry who
previously supplied sodium fluoride for
water fluoridation was facing a shortage of
fluorspar used in smelting aluminum. They
began to recover fluorine and make synthetic
fluorspar. Consequently, there was a
shortage of sodium fluoride to fluoridate
drinking water.
Ervin Bellack
and the industry seized the opportunity to
fill the gap in the market and dump the new
source of recovered pollution into America's
drinking water.
For the
phosphate fertilizer industry, the shortage
of sodium fluoride was the key to turning
red ink into black, and an environmental
liability into a perceived asset.
The
concentrated pollution could be dispersed
into drinking water throughout the United
States, one drop at a time.
With the help
of the USEPA and Ervin Bellack,
fluorosilicic acid was not regarded as
concentrated toxic waste anymore, a
liability. It became "FLUORIDE, the proven
cavity fighter."
USEPA and
U.S. Public Health Service waived all
testing procedures and expedited the
disposal of the radioactive concentrate into
America's drinking water as "New and
Improved FLUORIDE."
Immediately,
without any oversight and clinical or safety
studies, the U.S. Public Health Service and
American Dental Association encouraged
cities to use the pollution concentrate for
drinking water fluoridation.
1976, the
Resource Conservation and Recovery Act
(RCRA) opened the door for USEPA to work
with industry and actively find markets for
recovered pollutants such as fluorosilicic
acid.
By 1983 the
official USEPA policy was: "In regard to the
use of fluosilicic (fluorosilicic) acid as a
source of fluoride for fluoridation, this
agency regards such use as an ideal
environmental solution to a long-standing
problem. By recovering by-product
fluosilicic acid from fertilizer
manufacturing, water and air pollution are
minimized, and water utilities have a
low-cost source of fluoride available to the
communities." (Rebecca Hanmer, Deputy
Administrator, Office of Water, USEPA in
1983 correspondence to Dr. Leslie Russell
stated USEPA position on water
fluoridation).
While the EPA
Office of Drinking Water pushes the use of
pollution scrubber liquor as a drinking
water fluoridation agent, EPA Office of Air
and Radiation considers knowingly pumping
the same pollution into the atmosphere a
felony violation of the Clean Air Act. "40 CFR Part 63 [IL-64-2-5807; FRL-5656-4] RIN
2060-AE40 and 2060-AE44:
This action
proposes national emission standards for
hazardous air pollutants (NESHAP) for new
and existing major sources in phosphoric
acid manufacturing and phosphate fertilizers
production plants. Hazardous air pollutants
(HAPs) emitted by the facilities covered by
this proposed rule include hydrogen fluoride
(HF) ; arsenic, beryllium, cadmium,
chromium, manganese, mercury, and nickel
(HAP metals); and methyl isobutyl ketone (MIBK)
emissions. Human exposure to the HAP
constituents in these emissions may be
associated with adverse carcinogenic,
respiratory, nervous system, dermal,
developmental, and/or reproductive health
effects ."
In promoting the use of the pollution
concentrate as a fluoridation agent, the
ADA, Federal agencies and manufacturers
failed to mention that it was hot,
radioactive. Uranium and all of its decay
rate products are found in the raw phosphate
rock, fluorosilicic acid and in the
phosphate fertilizer. Before 1991, upwards
to 75% of the U.S. supply of uranium oxide
to fuel the nuclear industry was produced in
Central Florida. However, today, uranium is
not extracted because of economic reasons.
During the
wet process manufacturing trace amounts of
uranium and its decay rate products are
released and captured in the pollution
scrubber. As long as the amount of
contaminants added to the drinking water
(including radionuclides in fluorosilicic
acid) do not exceed the limits set forth in
the Safe Drinking Water Act , the EPA has no
regulatory problem with the use of any
contaminated products for drinking water
treatment.
While uranium
and radium found in fluorosilicic acid are
known carcinogens, two decay rate products
of uranium are even more dangerous and
carcinogenic: Radon-222 and Polonium-210 .
During the
acidulation process that creates phosphoric
acid, radon (a gas) contained in the
phosphate pebble can be released in greater
proportions than other decay rate products (radionuclides)
and carried over into the fluorosilicic
acid. Polonium may also be captured in
greater quantities during scrubbing
operations because like radon it is easily
soluble in acid and can readily combine with
fluoride.
USEPA is
responsible for regulating radionuclide
levels in the air and drinking water;
consequently, they are aware that Radon-222
decays into Lead-210 in 3.86 days. The lead
isotope and does not give off harmful alpha
radiation for twenty years until it turns
into Polonium-210. Unless someone knew to
look for specific isotopes, no one would
know that a transmutation to the extremely
radioactive Polonium-210 occurs .
The more
frightening aspects of the uranium decay
rate products is that a "half life" means
that one-half of the radionuclide decays to
the next product within a given amount of
time. In other words, when we are talking
about Polonium 210 (or whatever) lasting for
138 days, what actually
happens is that after 138 days (one half
life), half of the polonium will have
changed to something else, but half will be
still there. After another half life, it
will down to be a quarter activity, after
another half life it will be down to an
eighth - i.e. decreasing by half with each
half life; consequently, radionuclides are
the poison that keeps on poisoning in ever
diminishing amounts.
Polonium-210
may be the most insidious and most
significant health threat in the pollution
concentrate. Half of the polonium gives off
intense alpha radiation for 138 days until
it turns into regular lead and becomes
stable, however, half still remains emitting
alpha radiation for another 138 days, then a
quarter of the original amount and so on.
During the
decay period, a very small amount can be
very dangerous. The lead-210 isotope acts
like calcium in the body. It may lay stored
in the bone or body tissues for up to twenty
years before it explodes like a
carcinogenic, time released nuclear devices
as Polonium-210.
The
fluoridated water someone drinks today, may
be the cause of cancer twenty years down the
road. No one knows what the consequences of
using the pollution concentrate because
there has never been any clinical research
done with the product.
One particle
of Polonium-210 gives off 5,000 times more
alpha radiation than the same amount of
radium. Damage occurs in the body from
complete tissue absorption of the energy of
the alpha particle. Scientists say that
Polonium-210 can be carcinogenic to people
if exposed to more than 0.03 microcuries
(6.8 trillionths of a gram).
Scientists
write 6.8 trillionths of a gram as 6.8
x10-12g because it would appear as
0.0000000000068 grams. Figures like that are
hard to grasp to the average person, but
they show that polonium is harmful to humans
in very minute amounts.
Use of the
pollution concentrate to fluoridate drinking
water places one at risk continuously.
Drinking water fluoridated with
fluorosilicic acid contains radon at every
sequence of its decay to polonium. Also, the
fresher the batch of pollution concentrate,
the more polonium it will contain. The more
water fluoridated with the pollution
concentrate someone consumes, the better the
chances of developing cancer. It all boils
down to the luck of the draw. It all depends
on how much is stored in the body and in
what tissue.
The reason
the contaminated fluorosilicic acid is
allowed to be used for artificially
fluoridating drinking water is because it is
used in such small amounts. Federal
regulations would not be violated. However,
no clinical studies were ever performed with
the product.
While water
fluoridation proponents produce thousands of
clinical studies about fluoride, there is
not one clinical study done with the
pollution concentrate or typical tap water
containing fluorides.
Except the unwary public,
everyone involved
in the promotion and sale of the pollution
concentrate is aware that no clinical tests
have been done with the products. They are
also aware that radioactive and other
carcinogenic substances are contained in the
fluoridation agent. The contaminants could
be at levels that may pose a statistically
acceptable cancer risk to expendable subsets
of the population.
The USEPA and
Centers for Disease Control are aware of the
increased cancer risk from using the toxic
waste to fluoridate drinking water. However,
they have never commissioned or required any
clinical studies with the pollution
concentrate, specifically, the
hexafluorosilicate radical whose
toxicokinetic properties are different than
the lone, fluoride ion. In fact, the USEPA,
Fluoride: Regulatory Fact Sheet , 1997
states:
"Ideally, the
animal studies which support the fluoride
drinking water standards would exactly
replicate actual human exposure.
Unfortunately, due to varying human life
styles, diets, etc., this is not feasible.
Rather, EPA must make a judgement as to
whether a given animal study is or is not
relevant to humans."
Section 104
(I) (5) of CERCLA (Comprehensive
Environmental Response, Compensation and
Liability Act) directs the Administrator of
the Agency for Toxic Substances and Disease
Registry (consulting with the USEPA and the
Administrator of the USEPA and agencies and
programs of the U. S. Public Health Service)
with the National Toxicology Program to
initiate a program of research of fluorides
where adequate data is not available.
However, after almost 30 years of using fluorosilicic acid and sodium fluorosilicate
to fluoridate the drinking water, there has
not been one study commissioned with the
product. All clinical research with
animal models are done using 99.97% pure
sodium fluoride and double distilled or
deionized water.
All criteria
used to determine the safety of artificial
water fluoridation is based on the ideal
circumstance and not the complex reality of
the practice. Clinical studies done under
controlled conditions are the models used to
determine results of epidemiological and
population studies. However, the reality of
artificial drinking water fluoridation is
quite different.
There is no real quality control of the
product, and contaminants in the
fluorosilicic acid are contingent upon the
quality of the phosphate rock. Also, the
reaction of fluorosilicic acid with other
reactants (contaminants) in typical drinking
water may create complex ions, potentially
toxic ionic compounds. It is likely that
these complex ions are exponentially more
toxic than sodium fluoride dissolved in
distilled water.
The
fluorosilicic acid is also contaminated with
arsenic, cadmium, mercury, lead, sulfides,
iron and phosphorous, not to mention
radionuclides. Most of the contaminants
have the potential to react with the
hexafluorosilicate radical and may act as
complex ionic compounds. The biological
fates and toxicokinetic properties of these
complex ions are unknown.'The reality of
artificial water fluoridation is so complex
that determining the safety of the practice
is impossible.
Tap water is
chemically treated and often contains
contaminants that are unique to a particular
water system. The addition
of a fluoridation agent can create
synergized toxicants in a water supply that
have unique toxicokinetic properties found
only in that particular water supply.
Possible maladies resulting from chronic
ingestion of the product would be considered
an anomaly and not related to water
fluoridation in population or
epidemiological studies.
The
fluoridated water you drink is not the same
product as researched! The only similarity
is the fact that the fluoride ion is present
in some form. The fluoride ion only
hypothetically exists as an entity in an
ideal solution, purified water, and tap
water is far from pure H2O.
Vendors
selling the pollution concentrate as a
fluoridation agent use a broad disclaimer
found on the Material Data Safety Sheet: ".
. . In addition, no responsibility can be
assumed by vendor for any damage or injury
resulting from abnormal use, from any
failure to adhere to recommended practices,
or from any hazards inherent to the product."
The product
is a pollution concentrate, not fluorine or
fluoride as proponents state. Fluorine is
only another captured pollutant comprising
about 19% of the total product.
The next time
you turn on the tap and water gushes out
into a glass, reflecting on the USEPA
disclaimer before drinking may be a prudent
course of action.
"In the United States, there are
no Federal safety standards which are applicable
to additives, including those for use in
fluoridating drinking water."
(USEPA Fluoride: Regulatory
Fact Sheet. 1997). In essence, consume at
your own risk or "buyer beware."